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Super Clusters of Water Molecules
(H2O)100 stranded clusters
(H2O)280 super strand
(H2O)1820 super cluster
(H2O)100 stranded clusters
The smallest water cluster that may be stabilized by small hydrophobic molecules or kosmotropic ions
is the (H2O)100 cluster (see right or Java) that forms the central part of the (H2O)280 icosahedral cluster and as found in the cavity-encapsulated nanodrop of water in a polyoxomolybdate
. In this diagram, the oxygen atoms in the central (H2O)20 dodecahedron are colored blue.
The water clusters show increased stabilization in the order (H2O)20 < (H2O)100< (H2O)280 . However, the (H2O)100 clusters are somewhat stable as their hydrogen bonds are unstrained. Such clusters can form chains by linking through their outer pentameric (H2O)5 rings (forming partial structures from the ES (H2O)280 icosahedral cluster. Such partial structures involve fewer of the slightly strained hydrogen bonds present in the full ES (H2O)280 structure. They can form extensive networks such as the ordered network shown below. For clarity only the oxygen atoms are shown.
Such regular matrices are not generally expected. This structure is given as an example of some of the links available However randomly linked networks are possible and may be formed transiently at ambient temperatures and below. They would not be expected to be formed from whole (H2O)100 cluster units nor would they be distinct as other water molecules would hydrogen bond to the edges and faces individually and in clusters. (see Jmol, 850 KB)
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Super Strand of (H2O)280 Water Icosahedra
(H2O)280 icosahedral clusters may also form strands, albeit containing some more strained hydrogen bonds than the (H2O)100 strands. A super strand of eight water (H2O)280 icosahedra, showing the tessellation
ability, is illustrated below. Eight complete but overlapping icosahedral clusters form
this strand-like structure containing 1750 water molecules. For
clarity, only the oxygen atoms are shown (for interactive structures
This is shown
as an indicative example of the type of structure expected as water
is (super)cooled, so encouraging the expanded icosahedra (ES)
structures to increase their degree of structuring. These structures
are far less strained than more-symmetric supercluster
structuring and are as expected in the related low-energy minimal
polytetrahedral Dzugutov clusters where they are stabilized by the
presence of high barriers between potential energy minimal structures,
of particular importance at low temperatures .
Actual icosahedral strands are unlikely to be complete (as pictured),
but to contain partial additions or deletions and be of a variety
of lengths and shapes including partial or complete (H2O)100 strands. The presence of such clusters, in principle,
is in agreement with computer simulation studies 
and may explain the properties of deeply-supercooled water  as it is in agreement with such water being a good solvent for inert gas (Xenon) atoms, which fit well into the dodecahedral clathrate sites, but a very poor solven for salt (LiCl) , which would have to disrupt the hydrogen bonding. It would also possess the very low excess entropyand enthalpy of crystallization found .
Other liquids (similarly to deeply-supercooled water) have been found to solidify on heating. An aqueous solution of α-cyclodextrin and 4-methylpyridine is liquid below 45 °C then (reversibly) freezes (before 75 °C) to melt again at above 100 °C . The rationale is that the liquid phase contains mainly intramolecular hydrogen bonds but the solid phase contains intermolecular hydrogen bonds; a similar underlying principle to the proposal above.
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Icosahedral (H2O)1820 super cluster
super cluster of thirteen water icosahedra, showing the tessellation
ability. Thirteen complete but overlapping icosahedral clusters
form this super-icosahedral structure (an icosahedron of interpenetrating
icosahedra; that is, a tricontahedron) containing 1820
water molecules (an outer shell of an additional 360 water
molecules is also shown). This structure is for illustrative
purposes only of the type of superclustering possible. It
is not likely to be a preferred minimum-energy structure due
to the increased strain on full tessellation ;
However the icosahedral structures can form part of fully
tessellated clathrate I-type
The volume of the central (H2O)280 icosahedron is about 1/4 of the volume of a single gaseous
H2O molecule. Although there is presently no evidence
for this and the mechanism of formation is unclear, the stabilization
offered by the surrounding optimal hydrogen bonding may indicate
a possible route to bulk nanobubble (that is, nanocavity) formation. Only the oxygen atoms are shown (for interactive
structures see: Jmol).
coordinates and the spherical
shell radii of this structure are shown on other pages. Shown below is a cartoon showing the layered structure of this super cluster.